中國粉體網(wǎng)訊 透明鐵電材料可以將光學(xué)功能與壓電效應(yīng)耦合在一起,,為光聲成像系統(tǒng)、透明壓電致動器,、透明機(jī)器人等提供關(guān)鍵材料,。然而,壓電性,、透明性和居里溫度之間的相互制約關(guān)系使得制備同時具有高居里點,、高透明度和高壓電性的鐵電材料非常困難,這阻礙了其在多功能耦合器件領(lǐng)域的應(yīng)用,。
近日,,青島大學(xué)物理科學(xué)學(xué)院制備出Sm摻雜PIN-PMN-PT透明鐵電陶瓷。其居里溫度Tc~179 ℃,、壓電系數(shù)d33~905 pC/N,、電光系數(shù)r~814 pm/V、近紅外波段透光率63%,,綜合性能優(yōu)異,。與PMN-PT基透明陶瓷(Tc約100℃)相比,,PIN-PMN-PT透明陶瓷在壓電性能的溫度穩(wěn)定性方面表現(xiàn)優(yōu)異,。并且基于該透明陶瓷的電光效應(yīng)和壓電效應(yīng),實現(xiàn)了電光信息調(diào)制和能量轉(zhuǎn)換,。相關(guān)成果以"Sm-doped PIN-PMN-PT transparent ceramics with high Curie temperature, good piezoelectricity, and excellent electro-optical properties"為題發(fā)表在ACS Applied Materials & Interfaces上,。青島大學(xué)物理科學(xué)學(xué)院2019級碩士研究生鄭鳳基為該論文第一作者,青島大學(xué)張永成副教授為論文的通訊作者。
這一成果也是該團(tuán)隊在前期關(guān)于高電光性能PMN-PT透明陶瓷(Advanced Optical Materials, 9, 2002139 (2021))和高壓電性能PMN-PT透明陶瓷(ACS Appl. Mater. Interfaces, 13, 54210-54216(2021))研究基礎(chǔ)上取得的新進(jìn)展,。上述工作得到了國家自然科學(xué)基金,、山東省自然科學(xué)基金的支持。
圖1. Sm摻雜PIN-PMN-PT陶瓷的照片及透光率曲線,。
圖2.Sm摻雜PIN-PMN-PT透明陶瓷的鐵電,、壓電、介電性能的溫度穩(wěn)定性,。
圖3.Sm摻雜PIN-PMN-PT透明陶瓷的電光性能,。
圖4. PIN-PMN-PT透明鐵電陶瓷在電光調(diào)制和能量轉(zhuǎn)換中的應(yīng)用。
論文鏈接
https://doi.org/10.1021/acsami.2c19865
近期相關(guān)論文:
1. Fengji Zheng, Xue Tian, Yongcheng Zhang*, et al. Sm-Doped PIN-PMN-PT Transparent Ceramics with High Curie Temperature, Good Piezoelectricity, and Excellent Electro-Optical Properties, ACS Appl. Mater. Interfaces, 15, 7053−7062 (2023).
2. Ze Fang, Xiaodong Jiang, Yongcheng Zhang*, et al. Ultra-transparent PMN-PT Electro-Optic Ceramics and its Application in Optical Communication, Advanced Optical Materials, 9, 2002139 (2021).
3. Peikun Yan, Yalin Qin*, Yongcheng Zhang*, Shujun Zhang*,et al. Highly Transparent Eu-Doped 0.72PMN-0.28PT Ceramics with Excellent Piezoelectricity,ACS Appl. Mater. Interfaces, 13,54210-54216(2021).
4. Kai Li, Enwei Sun*, Yongcheng Zhang*, Bin Yang,*et al. High piezoelectricity of Eu3+-doped Pb(Mg1/3Nb2/3)O3–0.25PbTiO3transparent ceramics, Journal of Materials Chemistry C, 9, 2426-2436, (2021)
5. Ze Fang, Xue Tian, Yongcheng Zhang*, et al. Enhanced piezoelectric properties of Sm3+-modified PMN-PT ceramics and their application in energy harvesting, Ceramics International, 48, 7550–7556 (2022)
6. Shuang Zhang, Yongcheng Zhang*, Wanneng Ye* et al. In situ TEM observations of growth mechanisms of PbO nanoparticles from a Sm-doped PMN-PT matrix.Nanoscale, 14, 13801–13811(2022).
7. Ying Zheng, Yongcheng Zhang*, Wanneng Ye*, et al. Sm-Doped (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 Nanostructures for Piezocatalytic Dye Degradation. ACS Appl. Nano Mater, 5(1) 277–287(2022).
8. Mingqiang Cheng, Erding Zhao, Yongcheng Zhang*, et al. Ferroelectric and electromechanical performance of diverse engineered states of Mn-doped 0.75Pb(Mg1/3Nb2/3)O3-0.25PbTiO3ceramics. Ceramics International, 47,18417–18423(2021)
來源:作者團(tuán)隊
論文鏈接:https://doi.org/10.1021/acsami.2c19865
(中國粉體網(wǎng)編輯整理/山川)
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